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Dynamic Buffer Capacities in Redox Systems

Anna Maria Michalowska-Kaczmarczyk, Aneta Sporna-Kucab, Tadeusz Michalowski

The buffer capacity concept is extended on dynamic redox systems, realized according to titrimetric mode, where changes in pH are accompanied by changes in potential E values; it is the basic novelty of this paper. Two examples of monotonic course of the related curves of potential E vs. and pH vs. Φ relationships were considered. The systems were modeled according to GATES/GEB principles.

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